WHAT IS THE CAUSES

Anthropogenic sources (human activity) mostly related to burning different kinds of fuel
"Stationary Sources" include smoke stacks of power plants, manufacturing facilities (factories) and waste incinerators, as well as furnaces and other types of fuel-burning heating devices

"Mobile Sources" include motor vehicles, marine vessels, aircraft etc
Chemicals, dust and controlled burn practices in agriculture and forestry management. Controlled or prescribed burning is a technique sometimes used in forest management, farming, prairie restoration or greenhouse gas abatement. Fire is a natural part of both forest and grassland ecology and controlled fire can be a tool for foresters. Controlled burning stimulates the germination of some desirable forest trees, thus renewing the forest.
Fumes from paint, hair spray, varnish, aerosol sprays and other solvents
Waste deposition in landfills, which generate methane.Methane is not toxic; however, it is highly flammable and may form explosive mixtures with air. Methane is also an asphyxiant and may displace oxygen in an enclosed space. Asphyxia or suffocation may result if the oxygen concentration is reduced to below 19.5% by displacement
Military, such as nuclear weapons, toxic gases, germ warfare and rocketry

Natural sources

Dust from natural sources, usually large areas of land with little or no vegetation.
Methane, emitted by the digestion of food by animals, for example cattle.
Radon gas from radioactive decay within the Earth's crust.Radon is a colorless, odorless, naturally occurring, radioactive noble gas that is formed from the decay of radium. It is considered to be a health hazard.Radon gas from natural sources can accumulate in buildings, especially in confined areas such as the basement and it is the second most frequent cause of lung cancer, after cigarette smoking.
Smoke and carbon monoxide from wildfires.
Volcanic activity, which produce sulfur, chlorine, and ash particulates.